Tuesday, April 6, 2010

Chemistry Worksheet Review

 Chemistry Worksheet Review
    1. Significant Figures Practice worksheet with solutions for converting numbers bewteen the expanded form and the significant figure form.

   2. Adding and Subtracting Significant Figures

   3. Multiplying and Dividing Significant Figures


   4. Density Density practice worksheet and solutions.

   5. Unit Conversion Practice worksheet involving metric-metric and english-metric - great practice for chemistry students.

   6. Balancing Equations Practice sheet
   7. Formula Writing Practice worksheet with solutions for writing formulas/ Nomenclature
   8.  Atoms and Molecules


SIGNIFICANT FIGURES

 

The number of significant figures refers to the number of digits reported for the value of a measured or calculated quantity, indicating the precision of the value.

 

Rules for identifying the number of significant figures in a number.

1.      All digits are significant except zeros (zeros may or may not be significant)

2.      Placeholder zeros are not significant. Placeholder zeros would disappear if the number is placed in scientific notation. (Ex: 0.00025 has two significant figures 2 and 5)

3.      Terminating zeros ending to the left of the decimal point may not be significant. When the decimal point is not shown (Ex: 2000) you must assume that the zeros are NOT significant.

4.      Zeros are significant when they trail a number to indicate precision in the number. For example 0.05678000 ( the zeros to the left of 5 are not significant, but the three zeros following the 8 are, thus the digit contains seven significant figures)

5.      Zeros trapped between any two significant digits are significant. Ex: 5008 and 500.1

 

Find the number of significant digits in the following:

 

PROBLEM                              ANSWER

1.                  0.025                           _____________

2.                  54000                          _____________

3.                  0.005670                     _____________

4.                  2.40 x 104                    _____________

5.                  5007.00                       _____________

6.                  0.508                           _____________

7.                  0.0058363                   _____________

8.                  0.0600             _____________

9.                  34000.00                     _____________

10.              10200                          _____________

 

 

 

 


ANSWERS TO SIGNIFICANT FIGURES

1.                  2 – the zeros 0.025 are placeholders zeros only

2.                  2 – the zeros in 54000 are ambiguous since the decimal is not shown

3.                  4 – the 0.00 part is for place holder and the trailing zero is significant

4.                  3 – the zero indicates precision

5.                  6 – the zeros 5007.00 are trapped and 5007.00 indicate precision

6.                  3 – the zero 0.508 is place holding and 0.508 is trapped

7.                  5 – the zeros 0.0058363 are place holding

8.                  3 – the zeros 0.0600 are place holding and 0.0600 indicate precision

9.                  7 – the zeros 34000.00 indicate precision and 34000.00 are trapped

10.              3 – the zeros 10200 are ambiguous and 10200 is trapped

 


1)             25.01                                                       2)             150.3                     

     +  9.11                                                                       -107.240                                

                               

 

 

 

3)               24.0045                                                 4)                6.987

-   3.12                                                                    45.45

                          + 0.2      

 

 

 

 

5)                1543.02                                                6)               322.44                  

+  394.934                                                                    0.321

                                                                                    72.0

                                                                                -   68.9555

 

 

 

 

7)             553.24                                                    8)             439.00

               +   7                                                                         +  6.3

 

 

 

 

ANSWERS

1)                   34.12

2)                   43.06 à 43.1

3)                   20.8845 à 20.88

4)                   52.637 à 52.6

5)                   1937.954 à 1937.95

6)                   181.1635 à 181.5

7)                   560

8)                   445.3


1)       344.0 x 22.111                                                        2)             887.321 ¸ 54

 

 

 

 

3)     1645.54 x 0.1113 x 67.0                                          4)             22.091 ¸ (1.0 x 103) ¸ 0.999

 

 

 

 

5)     743.001 ¸ 0.0562                                                    6)             98.777 x 20.033 x 111 x 0.6577

 

 

 

 

7)     55601 ¸ 348 ¸ 3.0                                                  8)             4789.33 x 6871.00 x (2 x 102)

 

 

 

 

ANSWERS

1)                   7606.184 à 7,606

2)                   16.43187 à 16

3)                   12270.956 à 12,300

4)                   2.2113 x 10-2 à 2.2 x 10-2 or 0.022

5)                   13220.658 à 13,200

6)                   144461.67 à 144,000

7)                   53.257663 à 53

8)                   6.5815 x 109 à 7 x 109 or 7,000,000,000



DENSITY (remember you can always make the reciprocal of the given or a factor to get t o your answer
 

1.        What is the density of benzene in grams per milliliter if 5.5L of benzene weigh 4.8kg?

 

 

 

2.        The density of air is 1.3 g/L. How many liters of air weigh 2.0 lb?

 

 

 

3.        Given a cylinder with diameter of 39 mm and height of 39 mm, and mass of 1.0 Kg, what is it’s density?

 

 

 

4.        How many ounces does a 250ml sample of sulfuric acid weigh? (density = 1.30 g/ml)

 

 

 

 

5.        What is the density of the Earth if 1.00 yd3 weighs 22.0 lb? Express your answer in lb/ft3

 

 

 

6.        The density of brass is 8.0 g/ml. A cube of brass 2.0 inches on an edge will weigh how many grams?

 

 

 

7.        An unknown substance has a volume of 0.114 L and has a mass of 467g. What is its density in g/mL?

 

 

 

8. The density of Ethanoic Acetic Acid is 1.05 g/cm3. What is the mass in kilograms of a volume of 5L?

 

 

 

 

 

 

ANSWERS

1) D = mass   ?D=  4.8Kg  x  1000g  x  1L          = 0.87 g/mL

            vol                5.5L        1Kg         1000mL

 

 

2) V= m                   ?g = 2 lb  x  453.6 g  = 907.2 g

          D                                     1 lb

 

                                ?V = 907.2g   =  907.2g  x  1L   = 697.8 L

                                       1.3g                           1.3g

                                        1L

 

 

3)Volume of a cylinder  v= P r2h

r = ½ d, r = ½ (39mm) = 19.5 mm

v= P (19.5 mm)2(39mm) = 46589 mm3

 

? cm3 = 46589 mm3  x    (1m)3    x    (100cm)3  = 46.5 cm3

                                     (1000mm)3      (1m)3

 

D =   1 Kg      x    1000g  = 21.5 g/cm3

       46.5 cm3         1Kg

 

 

4) m= vD

?oz =  250ml  x  1.3g     x  1 oz      = 11.5 oz

                            1 mL      28.35 g

 

 

5) ? lb   =  22 lb  x  (1yd)3  = 0.815 lb/ft3

       ft3       1 yd3      (3ft)3

 

 

6) Volume of a cube v = s3

? v = (2in)3  x  (2.54 cm)3  = 131cm3

                           (1 in)3

 

? v = 131 cm3  x  1 mL  =  131 ml

                            1 cm3

 

m= vD = 131 mL  x  8g    = 1048g

                                 1 mL

 

 

7) D = m    = 467g     x     1 L    0.467 g/mL

            v        0.114L        1000mL

 

 

8) ? v = 5 L  x  1000mL  x  1 cm3  = 5000cm3

                          1L              1mL

 

?m = vD= 5000cm3  x  1.05g    x  1 Kg    =  5.25 Kg

                                      1 cm3        1000g



UNIT CONVERSIONS

Dimensional Analysis (Factor Label Method)

 

1.         1.2 kg              =          ________dg

 

 

2.         2.00 x 10-5m   =          ________in

 

 

3.         25.4 mm           =          ________cm

 

 

4.         1.2 miles           =          ________km

 

 

5.         15.47 m3          =          ________km3

 

 

6.         17.0 ft/s            =          ________m/min

 

 

7.         342 miles/hr      =          ________km/s

 

 

8.         45.1 yards        =          ________cm

 

 

9.         1.45 L              =          ________gallons

 

 

10.       4.100 g            =          ________mg

 

 

11.       1.2 kg/yard       =          ________lbs/m

 

 

12.       2.00ft3/min        =          ________L/hour

 

 

13.       145 ml              =          ________cm3 

 

 

14.       6.51 miles         =          ________cm

 

                                                                                               

ANSWERS

 

1.                  1.2 x 104 dg

2.                  7.87 x 10 –4 in

3.                  2.54 cm

4.                  1.9 km

5.                  1.547 x 10 –8 km3

6.                  311 m.min

7.                  0.153 km/s

8.                  4.12 x 103

9.                  0.383 gallon

10.              4.100 x 103 mg

11.              2.9 lbs/m

12.              3.40 x 103 L/hr

13.              145 cm3

14.              1.05 x 106 cm



BALANCING EQUATIONS
I am not including answers for these, I will check these on Friday when I see you and then email you answers on Friday.
Formatting was lost, but try to interpret the given questions to the best of your abilities :)

 

1.                  Al + Fe3O4          ------>         Al2O3 + Fe

 
  
 

3.         CH3OH + O2     ------>           CO2 + H2O

 

 

4.         P4O10 + H2O          ------>       H3PO4

 

 

5.         PCl5 + H2O     ------>              H3PO4 + HCl

 

 

6.         SbCl5 + H2O          ------>       SbOCl3 + HCl

 

 

7.         MgO + Si            ------>          Mg + SiO2

 

 

8.         CaCl2 + Na2CO3           ------>            CaCo3 + NaCl

 

 

9.         C6H6 + O2                ------>     CO2 + H2O

 

 

10.       Al2S3 + H2O            ------>      Al(OH)3 + H2S

 

 

11.       C2H6 + O2                ------>     CO2 + H2O

 

 

12.       KClO3   ------>         KCl + KClO4

 

 

13.       KBr + Cl                 ------>      KCl + Br2

 

 

14.       (NH4)2SO4 + NaOH          ------>       NH3 + H2O + Na2SO4/

 

 

15. Calcium Phosphate reacts with Sulfuric Acid to give Phosphic acid and Calcium Sulfate as a solid. Write the balanced equation for this reaction.


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WRITING FORMULAS

Write the correct chemical formula for the following:

 

   1.Magnesium Nitride

 

  2.Iron (III) Oxide


   3.Sodium Sulfate


   4.Copper (II) Chloride


   5.Barium Nitrate


   6.Aluminum Hydroxide


   7.Mercury (II) Phosphate


   8.Aluminum Silicate

   9. Copper (II) Bromide


   10.Lead (II) Chlorate


   11.Silver Cyanide



   12.Ammonium Oxide


   13.Aluminum Perchlorate


   14.Tin (II) Chloride

   15.Nickel (III) Acetate

   16.Potassium Sulfide

   17.Magnesium Bisulfate

   18.Iron (II) Phosphate

   19.Cobalt (II) Hydrogen Sulfate

   20.Chromium (II) Bicarbonate

   21.Sodium Hypochlorite

   22.Barium Carbonate

   23.Zinc (II) Permanganate








ATOMS AND MOLECULES
mol = 6.022 x 1023 particles

1 mol = 6.022 x 1023 atoms (use with molecular compounds)

1 mol = 6.022 x 1023 formula units (used with ionic compounds)

1 mol  = 6.022 x 1023 molecules

 

Atom- the smallest particle of an element that maintains its chemical identity through all chemical and physical changes.

Molecule- the smallest particle of an element or compound that can have a stable independent existence

Compound- a substance composed of two or more elements in fixed proportions

Element- a substance that cannot be decomposed into simpler substances by chemical means; composed of only one type of atom

Formula Unit- the smallest repeating unit of a substance; for non-ionic substances, the molecule.

Ion- an atom or group of atoms that carries an electrical charge; unequal # of protons and electrons

Molecular Compound- a compound that does not contain ions

Ionic Compound- a compound that is composed of cations and anions

 

MASS OF ONE MOLE OF ATOMS OF ELEMENTS

Element

# of Atoms in formula

Sample

Contains

Carbon: C

1 atom for each molecule

12.001g C

6.022 x 1023 C atoms or 1 mol of C atoms

6.022 x 1023 C molecules

Hydrogen: H2

2 atoms for each molecule

1.0079g H2

6.022 x 1023 H atoms or 1 mol of H atoms

3.011 x 1023 H2 molecules

Sulfur: S8

8 atoms for each molecule

32.066g S8

6.022 x 1023 S atoms or 1 mol of S atoms

0.75 x 1023 S8 molecules

 

MASS OF ONE MOLE OF MOLECULAR SUBSTANCES

Substance

Molecular Wt

Sample

# of Atoms in formula

Contains

Hydrogen

2.016

2.016g H2

2 H

6.022 x 1023 molecules or 1 mol of H2 molecules

2 * 6.022 x 1023 = 1.2044 x 1024 atoms of H or 2 mol of H atoms

Methane

16.04

16.04g CH4

1 C, 4 H

6.022 x 1023 CH4 molecules or 1 mol of CH4 molecules

6.022 x 1023 C atoms or 1 mol of C atoms

4 * 6.022 x 1023 = 2.4088 x 10 23 H atoms or 4 mol of H atoms

 

MASS OF ONE MOLE OF IONIC COMPOUNDS

Compound

Formula Wt

Sample with a Mass of  1 mol

# of Atoms in formula

Contains

Sodium Chloride

58.44

58.44 g NaCl

1 Na, 1 Cl

6.022 x 1023 Na+ ions or 1 mol of Na+ ions

6.022 x 1023 Cl- ions or 1 mol of Cl- ions

Aluminum Sulfate

342.1

342.1g Al2(SO4)3

2 Al, 3 (SO4)

2 * 6.022 x 1023= 1.2044 x 1024 Al+3 ions or 2 moles of Al+3 ions

3 * 6.022 x 1023= 1.8066 x 1024 SO4-2 ions or 3 moles of SO4–2 ions

 


MGCCC, Perk Learning Lab

TLM

 

CONVERTING ATOMS, MOLECULES & MOLES

 

1.        How many moles of atoms does 355.7 g of gold contain?

 

 

 

 

2.        Calculate the mass of one carbon atom in grams.

 

 

 

 

3.        How many (a) moles of Cl2 (b) Cl2 molecules and (c) Cl atoms are contained in 45 g of Chlorine gas (Cl2)?

 

 

 

 

 

 

 

 

 

4.        Calculate the number of (a) hydrogen, (b) oxygen and (c) sulfur atoms in 63g of sulfuric acid (H2SO4)

 

 

 
 
 
 
 
 
 
5.        A sample of metal contains 2.516 x 1023 atoms and has a mass of 82.29 grams. (a)How many moles of metal atoms are present in the sample? (b) What is the metal?

 

 

 

 

 

6. How many moles of O are in 6 moles of O3?

 

 

 

 
ANSWERS ON BACK

 

 


ANSWERS

1.             355.7g Au  *   1 mol Au atoms  = 1.805 moles of Au atoms

                                                196.97 g Au

 

2.                    12 g C             *        1 mol C atoms                     = 1.99 x 10-23 g C/ C atoms

 1 mol C atoms         6.022 x 10 23 C atoms

 

3.                    a. 45g Cl2  *           1 mol Cl2     = 0.635 mol Cl2

70.906 g Cl2

 

b. 0.635 mol Cl2       *      6.022 x 1023 molecules =  3.82 x 1023 Cl2 molecules

                                                                                1 mol Cl2

 

                c. 3.82 x 1023 Cl2 molecules     *           2 Cl atoms      =  7.64 x 1023 Cl atoms

                                                                                1 Cl2 molecule

 

4.             a. 63 g H2SO4  * 1 mol H2SO4  *    6.022 x 1023 molecules *     2 H atoms  =      7.7 x 1023 H atoms

                                             98 g H2SO4                1 mol H2SO4                       1 H2SO4 molecule

 

b. 63 g H2SO4  * 1 mol H2SO4  *    6.022 x 1023 molecules *     1 S atom  =      3.87 x 1023 S atoms

                                             98 g H2SO4                1 mol H2SO4                       1 H2SO4 molecule

 

c. 63 g H2SO4  * 1 mol H2SO4  *    6.022 x 1023 molecules *   4  O atoms  =    1.54 x 1024  O atoms

                                             98 g H2SO4                1 mol H2SO4                       1 H2SO4 molecule

 

5.             a.   2.516 x 1023 atoms   *    1 mol                        = 0.4178 mol of metal

                                                                6.022 x 1023 atoms

 

                b.    82.29 g    =  196.96 g/mol , Au (gold) is the metal

                       0.4178 mol

 

6.             6 mol O3   *          3 mol O   = 18 mol O

                                                1 mol O3




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